congodimple12
congodimple12
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This work presents a new insight on the design of high-performance photocatalysts for efficient degradation of typical air pollutants.Two biomass types of Botryosphaeria rhodina MAMB-05 (VMSM and M3) were evaluated to determine their effectiveness in removing Ag(I) ions from synthetic solutions. Both biomass types obtained good results in the biosorption process with maximum biosorption capacities (qm) for the Langmuir model of 34.67 and 39.23 mg Ag(I)/g dry biomass for M3 and VMSM, respectively. The biomass was characterized by X-ray microfluorescence and Fourier-transform-infrared spectroscopy (FT-IR). After the biosorption process, the mechanisms involved in biosorption were studied by FT-IR, X-ray diffraction (XRD), Field Emission Scanning Microscopy/Energy Dispersive X-ray Analysis (FESEM/EDX) and Ultraviolet-Visible Spectrophotometry. The results demonstrated the participation of various mechanisms in the retention of silver on biomass (bioadsorption, complexation, ion exchange, covalent bonding) that resulted in the formation of silver chloride nanoparticles (AgCl-NPs) and silver nanoparticles (AgNPs). The sizes of AgCl-NPs (chlorargyrite) according to the Debye-Scherrer equation were 19.29 nm (VMSM biomass) and 24.9 nm for the M3 type. For AgNPs the crystal size was between 1.5 and 0.8 nm for VMSM and M3 respectively. Furthermore, it was found that an undetermined fraction of the silver nanoparticles after biosorption remained in solution, which could be advantageous for their recovery.Caused by SARS-CoV-2, COVID-19 has become a severe threaten to society and human health, its epidemic control emerges as long-term issue. A sustainable epidemic and environmental transmission risk control (SEERC) in urban area is urgently needed. This work aims to conduct a new investigation on the transmission risk of SARS-COV-2 as virus/hazardous material through various environmental medias, routes and regions in the entirely urban area for guiding the SEERC. Specifically, 5 routes in 28 regions (totally 140 scenarios) are considered. For a new perspective, the risk evaluation is conducted by the quantification of frontline medicals staffs' valuable experience in this work. 207 specialists responsible for the treatment of over 9000 infected patients are involved. The result showed that degree of risk was in the order of breath>contact-to-object>contact-to-human>intake>unknown. The modeling suggested source control as the prior measure for epidemic control. The combination of source control & mask wearing showed high efficiency in SEERC. The homeworking policy needed to cooperate with activity limitation to perform its efficiency. Subsequently, a new plan for SEERC was discussed. DS-3201 EZH1 inhibitor This work delivered significant information to researchers and decision makers for the further development of sustainable control for SARS-COV-2 spreading and COVID-19 epidemic.Bioaugmentation is an important remediation strategy for hazardous organic compounds. A microcosm study was conducted to evaluate the remediation of soils contaminated with hazardous high explosive, Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) using an eco-friendly bioformulation. Janibacter cremeus, an enriched indigenous soil bacterium isolated from the explosive contaminated site was immobilized in a mixture of calcite and cocopeat for bioaugmentation. The developed bioformulation showed a consistent viability for 150 days, at 4 °C storage conditions. HMX at field concentrations was degraded in microcosms for 35 days under unsaturated (aerobic) and saturated (anoxic) moisture conditions. Negligible degradation was observed under unsaturated moisture conditions, whereas, saturated conditions led to substantial decrease in HMX. Mass spectrometric (MS) analysis revealed the formation of nitroso derivatives of HMX during the anoxic degradation. Also, observed was the presence of 5-hydroxy-4-nitro-2,4-diazapentanal, a precursor of 4- nitro-2,4-diazabutanal, which eventually could be mineralized. An inexpensive and natural carrier when chosen for immobilization of explosive degrading microbes was found to be effective in the in situ remediation of explosive.This study shows the technical feasibility to recover uranium from copper Pregnant Leaching Solutions (PLS) using ion-exchange, after a removal of chloride ions using the electrodialysis (ED) technique. The original copper PLS solutions came from the National Copper Corporation (CODELCO), from their hydrometallurgical operations, which contained high concentrations of chloride ions. These solutions contained average concentrations of 22 g/L chloride ions, pH 1.5 - 1.8 and 20 mg/L uranium. The high chloride contents made the uranium recovery technically unfeasible, because of the high volumes of chemical reagents needed to operate. To eliminate the chloride ions selectively, a modified electrodialysis (ED) process was developed. The ED process was made of a three-compartment cell. This system removed selectively the chloride ions, and replaced them with sulphuric ions, without modifying the composition of the copper PLS solution, to allow a continuous operation of the copper production plant. The ED process decreased the chloride content from 22 g/L to 6 g/L. Finally, static and dynamic load tests were performed for both the original PLS and the treated PLS, using 3 different anion-exchange resins Dowex-1, Lewatit A365 and Lewatit MP62-WS. The loading capacity of the ion-exchange resins was increased 4 times approximately. To assess the additive prognostic value of MR-based radiomics in predicting progression-free survival (PFS) in patients with nasopharyngeal carcinoma (NPC) METHODS Patients newly diagnosed with non-metastatic NPC between June 2006 and October 2019 were retrospectively included and randomly grouped into training and test cohorts (73 ratio). Radiomic features (n=213) were extracted from T2-weighted and contrast-enhanced T1-weighted MRI. The patients were staged according to the 8 edition of American Joint Committee on Cancer Staging Manual. The least absolute shrinkage and selection operator was used to select the relevant radiomic features. Univariate and multivariate Cox proportional hazards analyses were conducted for PFS, yielding three different survival models (clinical, stage, and radiomic). The integrated time-dependent area under the curve (iAUC) for PFS was calculated and compared among different combinations of survival models, and the analysis of variance was used to compare the survival models.

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