In comparison, SO2, a strong polar molecule, triggers the gate-opening effect in all three MOFs. Interestingly, a shape memory effect is observed for Cu(4-PyC)2 during the second SO2 sorption cycle. When comparing the different gate-opening pressures of each gas, we observed that the structural flexibility of the three frameworks is highly sensitive to the chemical hardness of the Lewis acidic metal ions (Mg2+ > Mn2+ > Cu2+). As a result, the gate opening behavior is observed at lower pressures for the MOFs containing weaker M-N bonds (harder metal ions), with the exception of Cu(4-PyC)2 toward C2H4. These observations reveal that different transition metals can be used to finely control the structural flexibility of the frameworks.Crystal phase, an intrinsic characteristic of crystalline materials, is one of the key parameters to determine their physicochemical properties. buy CRT0066101 Recently, great progress has been made in the synthesis of nanomaterials with unconventional phases that are different from their thermodynamically stable bulk counterparts via various synthetic methods. A nanocrystalline material can also be viewed as an assembly of atoms with long-range order. When larger entities, such as nanoclusters, nanoparticles, and microparticles, are used as building blocks, supercrystalline materials with rich phases are obtained, some of which even have no analogues in the atomic and molecular crystals. The unconventional phases of nanocrystalline and supercrystalline materials endow them with distinctive properties as compared to their conventional counterparts. This Review highlights the state-of-the-art progress of nanocrystalline and supercrystalline materials with unconventional phases constructed from multiscale building blocks, including atoms, nanoclusters, spherical and anisotropic nanoparticles, and microparticles. Emerging strategies for engineering their crystal phases are introduced, with highlights on the governing parameters that are essential for the formation of unconventional phases. Phase-dependent properties and applications of nanocrystalline and supercrystalline materials are summarized. Finally, major challenges and opportunities in future research directions are proposed.Chemical protein synthesis is a powerful avenue for accessing homogeneously modified proteins. While a significant number of small modified proteins bearing native post-translational modifications and non-natural modifications have been generated to date, access to larger targets has proved challenging. Herein, we describe the use of two ligation manifolds, namely, diselenide-selenoester ligation and native chemical ligation, to assemble a 31.5 kDa phosphorylated insulin-like growth factor binding protein (IGFBP-2) that comprises 290 amino acid residues, a phosphoserine post-translational modification, and nine disulfide bonds.The field of plasmonics is capable of enabling interesting applications in different wavelength ranges, spanning from the ultraviolet up to the infrared. The choice of plasmonic material and how the material is nanostructured has significant implications for ultimate performance of any plasmonic device. Artificially designed nanoporous metals (NPMs) have interesting material properties including large specific surface area, distinctive optical properties, high electrical conductivity, and reduced stiffness, implying their potentials for many applications. This paper reviews the wide range of available nanoporous metals (such as Au, Ag, Cu, Al, Mg, and Pt), mainly focusing on their properties as plasmonic materials. While extensive reports on the use and characterization of NPMs exist, a detailed discussion on their connection with surface plasmons and enhanced spectroscopies as well as photocatalysis is missing. Here, we report on different metals investigated, from the most used nanoporous gold to mixed metal compounds, and discuss each of these plasmonic materials' suitability for a range of structural design and applications. Finally, we discuss the potentials and limitations of the traditional and alternative plasmonic materials for applications in enhanced spectroscopy and photocatalysis.Lightweight electromagnetic (EM) wave absorbers made of ceramics have sparked tremendous interest for applications in EM wave interference protection at high temperatures. However, EM wave absorption by pure ceramics still faces huge challenges due to the lack of efficient EM wave attenuation modes. Inspired by the energy dissipation mechanism during fracture of lobster shells with a soft and stiff multilayered structure, we fabricate a high-performance EM wave absorption ceramic aerogel composed of an alternating multilayered wave transparent Si3N4 (N) layer and wave absorption SiC (C) layer by a simple restack method. The obtained N/C aerogel shows ultralow density (∼8 mg/cm3), broad effective absorption bandwidth (8.4 GHz), strong reflection loss (-45 dB) at room temperature, and excellent EM wave absorption performance at high temperatures up to 1000 °C. The attenuation of EM wave mainly results from a "reflection-absorption-zigzag reflection" process caused by the alternating multilayered structure. The superior absorption performance, especially at high temperatures, makes the N/C aerogel promising for next-generation wave absorption devices served in high-temperature environments.A transparent Ta3N5 photoanode is a promising candidate for the front-side photoelectrode in a photoelectrochemical (PEC) cell with tandem configuration (tandem cell), which can potentially provide high solar-to-hydrogen (STH) energy conversion efficiency. This study focuses in particular on the semiconductor properties and interfacial design of transparent Ta3N5 photoanodes fabricated on insulating quartz substrates (Ta3N5/SiO2), typically the geometric area of 1 × 1 cm2 in contact with indium on its edge. This material utilizes the self-conductivity of Ta3N5 to make the PEC system operational, and the electrode would strongly reflect the intrinsic nature of Ta3N5 without a back contact that is commonly introduced. First, PEC measurements using acetonitrile (ACN)/H2O mixed solution were made to elucidate the intrinsic photoresponse in the presence of tris(2,2'-bipyridine)ruthenium(II) bis(hexafluorophosphate) (Ru(bpy)3(PF6)2) without water contact which avoids a multielectron-transfer oxygen evolution reaction (OER) and photoinduced self-oxidation.