The exposure to TMX resulted in decreased activities of antioxidant enzymes, including superoxide dismutase (SOD), glutathione (GSH), and catalase (CAT), inducing oxidative stress and elevating malondialdehyde (MDA) concentration within the exposed groups. Degenerated luteal cells with vacuolation, in the corpus luteum, were detected in TMX-exposed animals via microscopic analysis after hematoxylin and eosin staining. A degenerated oocyte was found in a follicle, and the circular muscle layer exhibited degeneration/necrosis, accompanied by a substantial apoptotic cell rate. TMX triggered changes in the transcriptional regulation of apoptosis-related genes, thereby activating the intrinsic apoptotic pathway. In aggregate, the research findings support the hypothesis that TMX is toxic to the reproductive system of female Wistar rats.Our lives are dramatically transformed by the considerable advancement in nanotechnology. Nonetheless, the procedure carries with it a certain degree of environmental detriment. This research endeavors to leverage Helix aspersa, the land snail, as a bioindicator. During a two-week period, the spraying method was employed to administer titanium dioxide nanoparticles (TiO2NPs) at 70 and 140 g/L. Studies were conducted to ascertain oxidative biomarkers, condition index (CI), DNA damage, hemocyte count, and phagocytic activity. Through experimentation, the toxicity of TiO2NPs was determined, resulting in an LC50 value of 544 grams per liter. ch5424802 inhibitor Exposure to TiO2NPs significantly diminished the activity of both superoxide dismutase (SOD) and catalase (CAT) in the digestive gland of Helix aspersa. The catalase (CAT) activity measured at 3401 (P=0.0001), and SOD at 111 (P=0.00002), at a 140 g/L concentration after the two-week exposure. Glutathione peroxidase (GPX) activity demonstrated a value of 113001 units per milligram of protein when the concentration was 140 grams per liter, in contrast to the control group's higher activity of 547001 units per milligram of protein. Following the treatment, the hemocytes displayed DNA damage, demonstrated by the tail DNA percentage of 866002 and a tail moment of 52990 at 140 g/L, a statistically significant result (P=0002). The digestive gland displayed an elevation in both tail DNA percentage and tail moment, with the tail moment reaching 7838008 compared to the control's 229009 (P = 0.00001). The hemocyte population showed a marked reduction after two weeks, averaging 7115 per unit volume (140 g/L) compared to the control group's average of 7911. TiO2NPs demonstrably resulted in histological abnormalities affecting the digestive gland of the Helix aspersa mollusk. Based on the data, the Helix aspersa snail has the potential to function as a bioindicator for environmental pollution. In-depth analysis of the harmful effects produced by TiO2 nanoparticles, using in vivo models, must be conducted.The serious environmental problem of acid mine drainage (AMD) frequently occurs in mining areas. The effective management of AMD pollution demands a robust understanding of the key processes and pathways within hydrogeochemical evolution. Investigating the hydrogeochemical processes of groundwater pollution in the multi-aquifer system of the abandoned Dashu pyrite mine in Southwest China required both hydrogeochemical analysis and environmental isotope tracing. The water-rock interaction intensity was determined from an analysis of the deuterium excess parameter 'd' in groundwater samples and subsequent 2H, 18O, and T analysis results. Examining the distribution of d-T in the groundwater revealed the dominant source as the Quaternary reservoir platform's groundwater, and a close hydraulic connection among the various aquifers was apparent. The results of ion analysis and sulfur isotope tracing showed that groundwater sulfur was primarily derived from gypsum dissolution, whereas mine water sulfur was primarily derived from the oxidation of pyrite. Mining activities, as indicated by hydrogeochemical inversion results, modified water levels and flow patterns, stimulated water-rock interactions, changed hydrogeochemical processes, and led to cross-contamination between aquifer and mine water. Groundwater in depleted mining areas across multiple aquifers is impacted by pollution sources and critical hydrogeochemical processes, the understanding of which, as per the findings, provides both theoretical and practical frameworks for developing water source control and preventive approaches.The resolution of environmental problems and substantial economic gains were brought about by the comprehensive utilization of iron ore tailings (IOTs). The presented synthetic method, detailed in this study, offers a novel approach to creating ZSM-5 microspheres from IOTs. Utilizing diverse analytical methods, the effects of Si/Al molar ratios and the pH of the precursor solution on zeolite formation were investigated. Using the methanol-to-propylene (MTP) reaction, the catalytic activity of the catalyst prepared via solid-phase conversion (MP-ZSM-5) was assessed. The MP-ZSM-5 catalyst, prepared through an alternative method, outperforms the HM-ZSM-5 catalyst (prepared via the hydrothermal method) by not only increasing the catalytic lifetime from 187 hours to 360 hours but also displaying a higher propylene selectivity (437%) in comparison with the latter (386%). The TG results are subjected to analysis using the Kissinger-Akahira-Sunose (KAS) model to determine the kinetics of template removal. The activation energies needed for removing CTAB are 201,111,342 kJ/mol, and the activation energy for TPABr removal is 326,881,691 kJ/mol. This finding complements model-free kinetic algorithms to calculate the conversion and isoconversion of TPABr and CTAB degradation within ZSM-5, offering key insights for optimization in industrial production.The methodological approach detailed in this article involves the use of manganese (Mn3+Mn7+)-modified black titanium dioxide (Mn/BTiO2) as a photocatalyst to achieve optimized visible-light-driven photodegradation of treated agro-industrial effluent, TPOME. For the preparation of BTiO2, a tailored wet chemical process was adopted. Utilizing a wet impregnation technique with manganese, the BTiO2 was finally calcined at 300 degrees Celsius for one hour, yielding the Mn/BTiO2 product. We examined Mn/BTiO2's photocatalytic application in the removal of chemical oxygen demand (COD), phenolic compounds (PCs), color, and total organic carbon (TOC). Optimization of the photocatalytic process parameters, including photocatalyst loading, manganese concentration, hydrogen peroxide (H2O2) dose, and irradiation time, was undertaken using the design of experiments (DOE) technique. Employing optimal conditions, including a photocatalyst loading of 0.085 g/L, a H2O2 dose of 0.0048 mol/L, a manganese concentration of 0.301 wt.%, and 204 minutes of irradiation time, the removal efficiencies for COD, PCs, color, and TOC were 88.87%, 86.04%, 6.28%, and 84.66%, respectively. Statistical evaluation indicated that the response variable's removal from TPOME estimation yielded a highly significant R-squared value and remarkably low RMSE, MSE, MAD, MAE, and MAPE, thus showing high reliability in the results. Through this study, the developed photocatalytic system's considerable efficacy in treating waste effluent from the palm oil industry and similar agro-industrial sources was revealed, enabling the concurrent decrease of various organic pollution indicators.To prioritize nutrient-dense cuisine, a solar cooker is indispensable, eschewing the use of, and thus avoiding, LPG. Under present conditions, the solar cooker's application of a nanoparticle layer has demonstrably improved thermal performance and expedited the cooking process. Predicting thermal performance with the Fourier series was tried, and subsequently the study of cooking liquid temperatures was verified employing the Fourier series. The logical representation of the complete cooking process, considering weather factors, underwent a fuzzification process, yielding fuzzy rules. In order to corroborate the fuzzy inference, a thermal measurement of the cooking process was performed throughout the experiment. The study suggests that fuzzy logic modeling and Fourier series analysis can both be employed to simulate the proposed system, mirroring Chennai's local climate conditions across a range of comparable settings. Evaluating the total percentage reduction in carbon dioxide emissions during the use of a solar box cooker through an environmental and economic study, the results are contrasted with the greater dependence of Pt values. Minimizing CO2 emissions has a noticeable impact on Pt values. Boiling water yielded an overall efficiency of 526%, while oil at steady-state temperature reached 3899% efficiency.The struggle to obtain resources and the rising environmental concerns are motivating industrial manufacturing enterprises to establish a network characterized by interdependence. More sustainable industrial practices arise from the identification of symbiotic interactions. Despite this, the businesses found in these industrial parks are spread across numerous sectors. A sustainable symbiotic network in industrial parks is achievable only through a sector-by-sector analysis of the symbiotic relationships present within the park. In this way, the installation procedure for the symbiosis network will be smoother and more sustainable. This study, situated within this framework, has the goal of selecting the optimal sector for the creation of a symbiosis network, presenting an original methodology for assessing symbiosis potential. For this project, the criteria that dictated the implementation process and affected the network's symbiosis development were determined. A solution was achieved through the utilization of multi-criteria decision-making techniques to address the problem. In light of the process's inherent indeterminacies, fuzzy multi-criteria decision-making approaches were adopted. Henceforth, a decision-making model is presented to define the preferential sector, allowing for the construction of a symbiotic network in industrial parks. From the multi-criteria decision-making results, the number of enterprises that assess waste, specifically the count of customers having waste, is determined as the most important criterion.