F-V2O5-WO3/TiO2 catalysts were prepared by the impregnation method. As the content of F ions increased from 0.00 to 0.35 wt.%, the NO conversion of F-V2O5-WO3/TiO2 catalysts initially increased and then decreased. The 0.2F-V2O5-WO3/TiO2 catalyst (0.2 wt.% F ion) exhibited the best denitration (De-NOx) performance, with more than 95% NO conversion in the temperature range 160-360°C, and 99.0% N2 selectivity between 110 and 280°C. The addition of an appropriate amount of F ions eroded the surface morphology of the catalyst and reduced its grain size, thus enhancing the NO conversion at low temperature as well as the sulfur and water resistance of the V2O5-WO3/TiO2 catalyst. After selective catalytic reduction (SCR) reaction in a gas flow containing SO2 and H2O, the number of NH3 adsorption sites, active component content, specific surface area and pore volume decreased to different degrees. Ammonium sulfate species deposited on the catalyst surface, which blocked part of the active sites and reduced the NO conversion performance of the catalyst. On-line thermal regeneration could not completely recover the catalyst activity, although it prolonged the cumulative life of the catalyst. In addition, a mechanism for the effects of SO2 and H2O on catalyst NO conversion was proposed. V.Hydrilla verticillata (waterthyme) has been successfully used for phytoremediation in arsenic (As) contaminated water. To evaluate the effects of environmental factors on phytoremediation, this study conducted a series of orthogonal design experiments to determine optimal conditions, including phosphorus (P), nitrogen (N), and arsenate (As(V)) concentrations and initial pH levels, for As accumulation and biotransformation using this aquatic plant species, while also analyzing As species transformation in culture media after 96-hr exposure. Analysis of variance and the signal-to-noise ratio were used to identify both the effects of these environmental factors and their optimal conditions for this purpose. selleck Results indicated that both N and P significantly impacted accumulation, and N was essential in As species transformation. High N and intermediate P levels were critical to As accumulation and biotransformation by H. verticillata, while high N and low P levels were beneficial to As species transformation in culture media. The highest total arsenic accumulation was (197.2 ± 17.4) μg/g dry weight when As(V) was at level 3 (375 μg/L), N at level 2 (4 mg/L), P at level 1 (0.02 mg/L), and pH at level 2 (7). Although H. verticillata is highly efficient in removing As(V) from aquatic environments, its use could be potentially harmful to both humans and the natural environment due to its release of highly toxic arsenite. For cost-effective and ecofriendly phytoremediation of As-contaminated water, both N and P are helpful in regulating As accumulation and transformation in plants. V.Changes in solution chemistry and transport conditions can lead to the release of deposited MnO2 nanoparticles from a solid interface, allowing them to re-enter the aqueous environment. Understanding the release behavior of MnO2 nanoparticles from naturally occurring surfaces is critical for better prediction of the transport potential and environmental fate of MnO2 nanoparticles. In this study, the release of MnO2 nanoparticles was investigated using a quartz crystal microbalance with dissipation monitoring (QCM-D), and different environmental surface types, solution pH values and representative macromolecular organics were considered. MnO2 nanoparticles were first deposited on crystal sensors at elevated NaNO3 concentrations before being rinsed with double-deionized water to induce their remobilization. The results reveal that the release rate of MnO2 depends on the surface type, in the decreasing order SiO2 > Fe3O4 > Al2O3, resulting from electrostatic interactions between the surface and particles. Moreover, differences in solution pH can lead to variance in the release behavior of MnO2 nanoparticles. The release rate from surfaces was significantly higher at pH 9.8 that at 4.5, indicating that alkaline conditions were more favorable for the mobilization of MnO2 in the aquatic environment. In the presence of macromolecular organics, bovine serum albumin (BSA) can inhibit the release of MnO2 from the surfaces due to attractive forces. In presence of humic acid (HA) and sodium alginate (SA), the MnO2 nanoparticles were more likely to be mobile, which may be associated with a large repulsive barrier imparted by steric effects. V.Widespread usage of engineered metallic quantum dots (QDs) within consumer products has evoked a need to assess their fate within environmental systems. QDs are mixed-metal nanocrystals that often include Cd2+ which poses a health risk as a nanocrystal or when leached into water. The goal of this work is to study the long-term metal cation leaching behavior and the factors affecting the dissolution processes of mercaptopropionic acid (MPA) capped CdSe/ZnS QDs in aphotic conditions. QD suspensions were prepared in different water conditions, and release of Zn2+ and Cd2+ cations were monitored over time by size exclusion chromatography-inductively coupled plasma-mass spectrometry. In most conditions with dissolved O2 present, the ZnS shell degraded fairly rapidly over ~1 week, while some of the CdSe core remained up to 80 days. Additional MPA, Zn2+, and Cd2+ temporarily delayed dissolution, indicating a moderate role for capping agent detachment and mineral solubility. The presence of H2O2 and the ligand ethylenediaminetetraacetate accelerated dissolution, while NOM had no kinetic effect. No dissolution of CdSe core was observed when O2 was absent or when QDs formed aggregates at higher concentrations with O2 present. The shrinking particle model with product layer diffusion control best describes Zn2+ and Cd2+ dissolution kinetics. The longevity of QDs in their nanocrystal form appears to be partly controlled by environmental conditions, with anoxic, aphotic environments preserving the core mineral phase, and oxidants or complexing ligands promoting shell and core mineral dissolution. V.