are promising adsorbents for highly efficient phosphate removal and provide a new method to realize the resource utilization of copper tailings.Dissipation and transformation of cyantraniliprole, a new diamide class of insecticides, were investigated under greenhouse conditions, using snapdragon (Antirrhinum majus) as the model plant. RGFP966 Dissipation of cyantraniliprole in treated leaves was found to be dependent upon application methods (foliar spray versus soil drench) and doses (high versus low dose), with the parent insecticide being the major residue at various sampling points. A high-dose foliar application resulted in pesticide residue of 6.7-23.8 μg/g foliar fresh weight over 8 weeks of treatments, while in soil drench treatment the residue varied from 0.8 to 1.4 μg/g. However, the residue contents were similar between the two application methods at a low application dose. The transformation pathways of cyantraniliprole were primarily intramolecular rearrangements, with IN-J9Z38 being the major metabolite across treatments. Several other metabolites were also identified, some of which were unique to the application methods. Out of total 26 metabolites tentatively identified in this study, 10 metabolites were unique to foliar application, while six metabolites were unique to soil drench. In addition to plant-mediated biotransformation, photodegradation of the parent compound was identified as a potential mechanism in foliar application.Phosphate runoff from agriculture fields leads to eutrophication of the water bodies with devastating effects on the aquatic ecosystem. In this study, naturally occurring montmorillonite clay-incorporated iron crosslinked alginate biopolymer (MtIA) beads were synthesized and evaluated for aqueous phosphate removal. Batch experiment data showed an efficient phosphate removal (>99%) by the MtIA beads from solutions with different initial phosphate concentrations (1 and 5 mg PO43--P/L, and 100 μg PO43--P/L). The kinetic data fitted well into the pseudo-second-order kinetic model indicating chemisorption played an important role in phosphate removal. Based on analyses of results from the Elovich and intra-particulate diffusion models, phosphate removal by the MtIA beads was found to be chemisorption where both film diffusion and intra-particulate diffusion participated. The isotherm studies indicate that MtIA surfaces were heterogeneous, and the adsorption capacity of the beads calculated from Langmuir model was 48.7 mg PO43--P/g of dry beads which is ~2.3 times higher than values reported for other clay-metal-alginate beads. Electron microscopy (SEM-EDS) data from the beads showed a rough-textured surface which helped the beads achieve better contact with the phosphate ions. Fourier-transform infrared spectroscopy (FTIR) indicated that both iron and montmorillonite clay participated in crosslinking with the alginate chain. The MtIA beads worked effectively (>98% phosphate removal) over a wide pH range of 2-10 making it a robust adsorbent. The beads can potentially be used for phosphate recovery from eutrophic lakes, agricultural run-off, and municipal wastewater.In the last years, uncontrolled fires are frequently occurring in forest and agricultural areas as an indirect effect of the rising aridity and global warming or caused by intentional illegal burnings. In addition, controlled burning is still largely used by farmers as an agricultural practice in many parts of the world. During fire events, soil can reach very high temperatures at the soil surface, causing dramatic changes of soil properties and elements biogeochemistry. Among soil elements, also potentially toxic elements (PTEs) can be affected by fires, becoming more or less mobile and bioavailable, depending on fire severity and soil characteristics. Such transformations could be particularly relevant in agricultural soils used for crop productions since fire events could modify PTEs speciation and uptake by plants and associated (micro)organisms thus endangering the whole food-chain. In this review, after describing the effects of fire on soil minerals and organic matter, the impact of fires on PTEs distribution and speciation in soils is presented, as well as their influence on soil microorganisms and plants uptake. The most common experimental methods used to simulate fires at the laboratory and field scale are briefly illustrated, and finally the impact that traditional and innovative agricultural practices can have on PTEs availability in burned agricultural soils is discussed in a future research perspective.The reactivity of zero-valent iron (ZVI) for the Cr(VI) removal in groundwater is mainly limited by the formation of a passivation layer during its application in permeable reactive barrier (PRB). A kind of sulfidated copper-iron bimetal (S-ZVICu) with high reactivity for Cr(VI) removal was prepared by depositing FeSx onto copper modified ZVI via a one-pot method. The surface characteristic, reactivity and Cr(VI) removal performance of S-ZVICu were investigated. It was found that S-ZVICu had a Cr(VI) removal capacity as high as 67.5 mg/g and little risk of secondary contaminant of Cu(II). The optimal Cu/Fe mass ratio and S/Fe molar ratio were 0.0125 and 0.084, respectively. The S-ZVICu exhibited great superiority of Cr(VI) removal compared with ZVI, sulfidated ZVI (SZVI) and coper-iron bimetal (ZVICu). Mineralogy and morphology analysis showed that S-ZVICu had a hierarchical structure of Fe0/Cu0/FeSx, which could effectively reduce the risk of secondary contaminant of copper ions. The mechanism analysis suggested that the copper and FeSx successively plated on the surface of ZVI played a dual role in promoting the corrosion of zero-valent iron, and was facilitated to electron transfer between Fe0, Cu0, FeSx and Cr(VI). In addition, the loose FeSx layer had a positive effect on alleviating the oxidation of ZVI in air, which was helpful in maintaining the reactivity of S-ZVICu in the air. S-ZVICu is an environmentally friendly material for sustainable and effective removal of Cr(VI) in groundwater.Plastic pollution in the form of nanoplastics poses a global threat to aquatic ecosystems and the organisms inhabiting them. However, few studies have been conducted on the effects of nanoplastic exposure on reproductive development in crustaceans. In order to address this issue, juvenile oriental river prawns (Macrobrachium nipponense) were exposed to different concentrations of 75-nm polystyrene nanoplastics (0, 5, 10, 20, 40 mg/L) for 28 days. In order to study the regulation of reproduction-related genes in the presence of nanoplastics, the Wee1 protein kinase gene (Wee1) and OTU domain ubiquitin aldehyde binding protein gene (OTUB) were selected. In this study, for the first time, the full-length cDNA of Mn-Wee1 and Mn-OTUB were cloned from M. nipponense. Homologous alignments revealed that Mn-Wee1 had a highly conserved function-critical sequence, and that Mn-OTUB was more closely related to OTUB1 than OTUB2. With increasing concentration of nanoplastics, the expression of both genes increased initially, then decreased.